My main experience with colour temperature started with LF (large format) film, where it is possible to define the temperature for each sheet of film. My film of choice is Velvia 100 transparency film, which is balanced for 5600°K.
So, every shot I take has to be balanced to that temperature in order to avoid horrendous casts, by using colour correction filters that are various degrees of blue or orange, in order to offset any cast produced by the ambient light.
Needless to say, for film, I use a colour meter that not only takes a reading of the light, it also tells me which filter(s) to use.
I made a small series of digital example images that demonstrates how the direction you are shooting in affects either the filter requirement for film or the WB for digital.
To start with, I shot with the light coming from behind me and, with AWB, got this…
I measured the temperature of the light with my colour meter and it gave me 5150°K, so I used PL to set that temperature and got…
Not too much difference but still noticeable.
Then I turned the chair around , so the light was coming from in front of me and, with AWB, got this…
I measured the temperature of the light with my colour meter and, this time, it gave me 8580°K, so, again, I used PL to set that temperature and got…
Now, the measured and corrected shots look very different but, if I take a crop out of both shots, and place them side by side…

… you can see they are identical.
In your image, Mike, the light is coming from behind and to the right and the majority is in shadow so, if anything, the image is going to be fairly cool and, as you found, the white van gives a “bluish” temperature. But, if you measure the sunlit building in the distance, you get a warm rendering. Both of which are not “right” - which is why. I stuck with 5600°K, so most of the image looks “right”.
My normal practice for digital WB is to always shoot at “daylight film” temperature (5600°K) and then decide what I want to be pure white, if anything, in PL and use the pipette on that. But that is not always the case because I may want to evoke a certain atmosphere of warmth or coolness and, since I am not shooting for a catalogue, where absolute colour matching is important, having the camera always taking at a fixed temperature and tint (5600/0) allows me to adjust the ambiance in PL more easily.
Finally, don’t rely on PL for absolute colour temperatures, My Nikon D850, set to 5600/0 usually comes into PL at 5643/-3, but that has changed as PL has been updated.
PL’s idea of “daylight” is 5200, which I’m guessing is to match digital screens but is way too cool for my taste. And, in the end, how white your whites are is all a matter of personal taste, not fact.